Team:UCLA/Notebook/Materials/3 September 2015
Trying a new HFIP Spin
- 57 mg of lyophilized silk in 228 uL of HFIP
- we are melting it inside of the syringe body
Dialyzing the LiBr silk
- dialysis start: 11:30AM
- change 1: 12:30PM
Trying Honeybee Silk Spin
- unknown concentration
- 10 uL/min
- Tried a variety of coagulation baths
- 100% Methanol
- 90% Methanol
- 80% Methanol
- 70% Methanol
- 100% water
- 100% Isopropanol
- 70% Isopropanol
- Note: The silk gels up in the syringe barrel at room temperature.
- This silk behaves very strangely
- You see those "ghost" wisps that look like solvent
- But occasionally, an opaque thread will come out at very high speed
- It looks like the gel in the barrel
- It will travel down into the beaker, then disintegrate
- At higher alcohol concentrations, the "thread" does appear to coagulate and bunch up near the tip (as the literature says it would)
- I think that the dope is too dilute.
- But also, the fact that it's gelling in the barrel is disconcerting.